Meerwein-Ponndorf-Verley Reduction and Oppenauer Oxidation Catalyzed by Heterogeneous Catalysts

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  • M. Bartosova Department of Organic Technology, Institute of Chemical Technology, Prague,
  • L. Cerveny Department of Organic Technology, Institute of Chemical Technology, Prague,
  • B. Wichterlova Jaroslav Heyrovsky Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Prague

Abstrakt

The article summarizes literature findings on Meerwein-Ponndorf-Verley oxidations on heterogeneous catalysts. including amorphous metallic oxides and zeolites that exhibit surface basicity or Lewis acidity. Attention is primarily focused on catalytic properties of high-silicate zeolites of ß-structure based on alumosilicates and titanosilicates. The reaction mechanism and high cis stereoselectivity of the catalysts are discussed. The reactions find use in the field of specialty chemicals.

Publikováno

15.06.2001

Jak citovat

Bartosova, M., Cerveny, L., & Wichterlova, B. (2001). Meerwein-Ponndorf-Verley Reduction and Oppenauer Oxidation Catalyzed by Heterogeneous Catalysts. Chemické Listy, 95(5). Získáno z http://ww.chemicke-listy.cz/ojs3/index.php/chemicke-listy/article/view/2417

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